Bis(acetato-κO)bis(thiourea-κS)cobalt(II)
نویسنده
چکیده
The title compound, [Co(CH3COO)2(CH4N2S)2], is isotypic with the corresponding Zn(II) complex. The metal atom is in a distorted tetra-hedral coordination environment with the two S atoms from two thio-urea ligands and two O atoms from two acetate anions as the coordinating atoms. All H atoms of the thio-urea ligands are involved in N-H⋯O and N-H⋯S hydrogen bonds, leading to a three-dimensional network.
منابع مشابه
(Acetato-κO)(acetato-κO,O′)bis(1,3-diazinane-2-thione-κS)cadmium(II)
In the title complex, [Cd(CH(3)COO)(2)(C(4)H(8)N(2)S)(2)], the Cd(II) cation is coordinated by three acetate O atoms and two S atoms of Diaz [Diaz = 1,3-diazinane-2-thione = 3,4,5,6-tetra-hydro-pyrimidine-2(1H)-thione]. The Cd(II) coordination is augmented by one considerably longer Cd-O bond of 2.782 (3) Å to a carboxyl-ate O atom. The resulting coordination polyhedron around the Cd(II) cation...
متن کاملBis(μ-3-nitrophthalato-κ2 O 1:O 2)bis[(thiourea-κS)zinc] dihydrate
In the title complex, [Zn(2)(C(8)H(3)NO(6))(2)(CH(4)N(2)S)(4)]·2H(2)O, the carboxyl-ate groups of the 3-nitro-phthalate ligands coordinate in a bis-monodentate mode to the Zn(II) cations. This results in the formation of a centrosymmetric dimer containing two Zn(II) cations with distorted tetra-hedral geometries provided by the O atoms of two different 3-nitro-phthalate dianions and the S atoms...
متن کامل(Acetato-κO){bis[(2,4-dimethyl-1H-pyrazol-1-yl)methyl][(pyridin-2-yl)methyl]amine}cobalt(II) hexafluoridophosphate
In the title compound, [Co(CH(3)CO(2))(C(18)H(24)N(6))]PF(6), the Co(II) atom is penta-coordinated in a distorted trigonal-bipyramidal geometry by four N atoms from a tripodal ligand and one O atom from a monodentate acetate ligand. The crystal packing is stabilized by inter-molecular C-H⋯F and C-H⋯O hydrogen bonds.
متن کاملBis(μ2-quinoline-2-carboxylato)-κ3 N,O 1:O 1;κ3 O 1:N,O 1-bis[(acetato-κO)(ethanol-κO)lead(II)]
In the centrosymmetric dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(C(2)H(5)OH)(2)], one O atom of the carboxyl-ate group of the quinoline-2-carboxyl-ate anion connects the two Pb(II) atoms. The Pb(II) atom is surrounded by four O atoms and one N atom in a Ψ-octa-hedral PbO(4)NE geometry (E is the electron lone pair). Two longer Pb⋯O inter-actions distort the geometry toward...
متن کاملBis(acetato-κO)bis(4,5-dimethylbenzene-1,2-diamine-κN)zinc
The structure of the title compound, [Zn(CH(3)COO)(2)(C(8)H(12)N(2))(2)], has one half molecule in the asymmetric unit. The Zn(II) atom is situated on a twofold rotation axis and is tetrahedrally coordinated by two N and two O atoms. The crystal packing displays inter-molecular N-H⋯O hydrogen bonds and intra-molecular N-H⋯O and N-H⋯N hydrogen bonding.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 70 شماره
صفحات -
تاریخ انتشار 2014